Data from NASA's Phoenix Mars Lander suggest liquid water has interacted with the Martian surface throughout the planet's history and into modern times. The research also provides new evidence that volcanic activity has persisted on the Red Planet into geologically recent times, several million years ago. Although the lander, which arrived on Mars on May 25, 2008, is no longer operating, NASA scientists continue to analyze data gathered from that mission. These recent findings are based on data about the planet's carbon dioxide, which makes up about 95 percent of the Martian atmosphere. "Atmospheric carbon dioxide is like a chemical spy," said Paul Niles, a space scientist at NASA's Johnson Space Center in Houston. "It infiltrates every part of the surface of Mars and can indicate the presence of water and its history."
Phoenix precisely measured isotopes of carbon and oxygen in the carbon dioxide of the Martian atmosphere. Isotopes are variants of the same element with different atomic weights. Niles is lead author of a paper about the findings published in Thursday's online edition of the journal Science. The paper explains the ratios of stable isotopes and their implications for the history of Martian water and volcanoes. "Isotopes can be used as a chemical signature that can tell us where something came from, and what kinds of events it has experienced," Niles said. This chemical signature suggests that liquid water primarily existed at temperatures near freezing and that hydrothermal systems similar to Yellowstone’s hot springs have been rare throughout the planet's past.
Measurements concerning carbon dioxide showed Mars is a much more active planet than previously thought. The results imply Mars has replenished its atmospheric carbon dioxide relatively recently, and the carbon dioxide has reacted with liquid water present on the surface. Measurements were performed by an instrument on Phoenix called the Evolved Gas Analyzer. The instrument was capable of doing more accurate analysis of carbon dioxide than similar instruments on NASA's Viking landers in the 1970s. The Viking Program provided the only previous Mars isotope data sent back to Earth. The low gravity and lack of a magnetic field on Mars mean that as carbon dioxide accumulates in the atmosphere, it will be lost to space. This process favors loss of a lighter isotope named carbon-12 compared to carbon-13.
Experiments prompted by a 2008 surprise from NASA's Phoenix Mars Lander suggest that soil examined by NASA's Viking Mars landers in 1976 may have contained carbon-based chemical building blocks of life. "This doesn't say anything about the question of whether or not life has existed on Mars, but it could make a big difference in how we look for evidence to answer that question," said Chris McKay of NASA's Ames Research Center, Moffett Field, Calif. McKay coauthored a study published online by the Journal of Geophysical Research - Planets, reanalyzing results of Viking's tests for organic chemicals in Martian soil.
The only organic chemicals identified when the Viking landers heated samples of Martian soil were chloromethane and dichloromethane chlorine compounds interpreted at the time as likely contaminants from cleaning fluids. But those chemicals are exactly what the new study found when a little perchlorate the surprise finding from Phoenix was added to desert soil from Chile containing organics and analyzed in the manner of the Viking tests. "Our results suggest that not only organics, but also perchlorate, may have been present in the soil at both Viking landing sites," said the study's lead author, Rafael Navarro-González of the National Autonomous University of Mexico, Mexico City.
Organics can come from non-biological or biological sources. Many meteorites raining onto Mars and Earth for the past 5 billion years contain organics. Even if Mars has never had life, scientists before Viking anticipated that Martian soil would contain organics from meteorites. "The lack of organics was a big surprise from the Vikings," McKay said. "But for 30 years we were looking at a jigsaw puzzle with a piece missing. Phoenix has provided the missing piece: perchlorate. The perchlorate discovery by Phoenix was one of the most important results from Mars since Viking." Perchlorate, an ion of chlorine and oxygen, becomes a strong oxidant when heated. "It could sit there in the Martian soil with organics around it for billions of years and not break them down, but when you heat the soil to check for organics, the perchlorate destroys them rapidly," McKay said.
NASA's Phoenix Mars Lander has ended operations after repeated attempts to contact the spacecraft were unsuccessful. A new image transmitted by NASA's Mars Reconnaissance Orbiter (MRO) shows signs of severe ice damage to the lander's solar panels.
"The Phoenix spacecraft succeeded in its investigations and exceeded its planned lifetime," said Fuk Li, manager of the Mars Exploration Program at NASA's Jet Propulsion Laboratory in Pasadena, Calif. "Although its work is finished, analysis of information from Phoenix's science activities will continue for some time to come."
Last week, NASA's Mars Odyssey orbiter flew over the Phoenix landing site 61 times during a final attempt to communicate with the lander. No transmission from the lander was detected. Phoenix also did not communicate during 150 flights in three earlier listening campaigns this year.Earth-based research continues on discoveries Phoenix made during summer conditions at the far-northern site where it landed May 25, 2008. The solar-powered lander completed its three-month mission and kept working until sunlight waned two months later.
Data from NASA's Phoenix Mars Lander suggest liquid water has interacted with the Martian surface throughout the planet's history and into modern times. The research also provides new evidence that volcanic activity has persisted on the Red Planet into geologically recent times, several million years ago. Although the lander, which arrived on Mars on May 25, 2008, is no longer operating, NASA scientists continue to analyze data gathered from that mission. These recent findings are based on data about the planet's carbon dioxide, which makes up about 95 percent of the Martian atmosphere. "Atmospheric carbon dioxide is like a chemical spy," said Paul Niles, a space scientist at NASA's Johnson Space Center in Houston. "It infiltrates every part of the surface of Mars and can indicate the presence of water and its history." 
